Based on the research of occupation values among university students from poor family,the paper analyzed the results which reflected the students willingness to accept the education mechanism of occupation values,combining with ideological and political education at present situation,and it put forward a practical program to enhance the effect of vocational education.This paper studied the new breakthrough method of improving the practical value of vocational education for these students,and made further exploration on-theoretical issues and practical solutions,which was constructive and meaningful to relevant theoretical research and practical operation.